Co_2(CO)_6(TPPTSLn)_2xH_2O配合物的合成

Synthesis of Co 2(CO) 6(TPPTSLn) 2· x H 2O Complexes

研究了数种轻稀土（Ｌａ，Ｓｍ，Ｇｄ，Ｙ）的Ｐ（ｍ－Ｃ６Ｈ５ＳＯ３）３Ｌｎ盐与ＣＯ２（ＣＯ）８形成的配合物的合成方法，探讨了温度，时间等因素对配合物形成的影响。

The synthesis and characterization of a series of watersoluble cobalt carbonyl complexes,Co 2(CO) 6(TPPTSLn) 2.xH 2O,are described,where TPPTSLn=P(m-C 6H 4SO 3) 3 Ln,Ln=La、Sm、Y、Gd.The reaction conditions such as temperature and time etc.are discussed.