摘要
在Mo-Ce/SiO_2催化剂上甲醇氧化制甲醛的动力学方程可表达为甲醇及甲醛吸附的Redox机理方程,当催化剂颗粒直径增大到3mm时,内扩散强烈地影响反应速度。催化剂有效因子η可用一般速度方程的近似方法进行解释。催化剂孔内甲醇的压力分布可用下式求得:
The kinetics of oxidation of methanol to formaldehyde over Mo-Ce/SiO2 catalyst might be described by the equation of Redox mechanism with adsorption of methanol and.formaldehyde. When the particle size of catalyst reached 3 mm in diameter, intraparticle diffusion affected the reaction rate strongly. The effectiveness factors of catalyst were determined by experiments and interpreted by the approximation method of general rate equation. .The pressure of methanol in catalyst pore might be obtained by equation
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
1990年第8期843-847,共5页
Chemical Journal of Chinese Universities
关键词
甲醇
氧化
甲醛
Mo-Ce/Sio2
Oxidation of methanol to formaldehyde, Effectiveness factor, Pressure profile of methanol