摘要
铑催化不对称1,4-共轭加成反应是一种非常有效的碳—碳键形成方法.综述了近年来铑催化不对称1,4-共轭加成反应的研究进展,包括α,β-不饱和酮、酯、酰胺、醛和砜等与某些亲核试剂的1,4-共轭加成反应.
Rhodium-catalyzed asymmetric 1,4-conjugate addition reaction is one of the most efficient methods for the carbon-carbon bond formation. In this paper, the recent progress in rhodium-catalyzed asymmetric 1,4-conjugate addition reactions is reviewed. Asymmetric 1,4-conjugate additions of α,β-unsaturated ketones, esters, amides, aldehydes, sulfones and so on with some nucleophiles are presented.
出处
《有机化学》
SCIE
CAS
CSCD
北大核心
2007年第7期806-818,共13页
Chinese Journal of Organic Chemistry
基金
广东省自然科学基金(No.04010404)资助项目.
关键词
铑催化
不对称
亲核试剂
1
4-共轭加成
rhodium-catalyzed
asymmetric
nucleophile
1,4-conjugate addition
