深入理论研究碰撞转动传能量子干涉效应的微分干涉角(英文)

Further theoretical study of the differential interference angle of collisional quantum interference on rotational energy transfer

分子内部转动传能的静态池实验观察到了碰撞量子干涉效应(CQI),并且测得积分干涉角,为了获得更加精确的分子内部转动传能的碰撞量子干涉效应信息,实验就必须要采用分子束实验进行.本文理论上采用各项异性相互作用势,应用含时微扰理论的一级波恩近似,假想在分子束实验的条件下,建立在原子—双原子分子体系中碰撞量子干涉的理论模型.理论上推导出微分干涉角具体表达式,通过计算定性地讨论了微分干涉角随着碰撞参数、速率等的变化趋势,同时初步探讨了实验的正确观测途径,得出了采用分子束进行实验观测的实验方法,为进一步进行分子束实验提供了理论基础,对实验的进行起到了一定的借鉴作用.

Collisonal quantum interference（CQI）was observed in the intramolecular rotational energy transfer in the experiment of the static cell, and the integral interference angles were measured. To observe more precise information, the experiment in the molecular beam should be taken, from which the differential interference angle can be obtained precisely. In this paper,the theoretical model of CQI is described in an atom-diatom system in the condition of the molecular beam, based on the first-Born approximation of time dependent perturbation theory, taking into accounts the anisotropic Lennard-Jones interaction potentials. The method of observing and measuring correctly the differential interference angle is presented. The changing tendencies of the differential interference angle with the impact parameter, velocity, and et al. are discussed.