载体及活性组份对聚合物负载铑络合物的催化醛化性能和稳定性的影响

THE EFFECT OF THE SUPPORTS AND ACTIVE SPECIES ON THE REACTIVITY AND STABILITY OF POLYMER-SUPPORTED RHODIUM COMPLEXES IN HYDROFORMYLATION

本文研究了载体和活性组份(包括载体交联度、孔径、比表面及铑负载量等因素)对聚合物负载铑络合物在己烯-1氢甲酰化反应中的催化性能与稳定性的影响。

Effects of supports and active sepcies, including the degree of croslinking, specific surface area, pore radius of supports and the loading of rhodium etc., on the catalytic properties and stability of polymer-supported rhodium complexes in hydroformylation of 1-hexene were studied under batch reaction conditions. From the experimental results, it was found that these factors show certain influence on rhodium elution.