聚酮聚合物的合成研究——影响聚酮分子量的几个主要因素
摘要
采用过渡金属钯催化乙烯与CO共聚合成聚酮,用红外分析和元素分析的方法对聚酮的结构进行了表征;分别研究了酸的种类、三氟乙酸的用量、稀释剂的种类以及甲醇的用量对聚酮分子量的影响。
出处
《纺织科学研究》
2007年第2期26-30,56,共6页
Textile Science Research
参考文献6
-
1王天民.环境材料导论[M].北京:化学工业出版社,1997.1~3.
-
2Wilhelmus P Mul, Hendrik Dirkzwager, Antonius A Broekhuis. Highly active, recyclable catalyst for the manufacture of viscous, low molecular weight, CO--ethene-propene-based polyketone, base component for a new class of resins[J]. Inorganica Chimica Acta, 2002, 327:147 - 159.
-
3W C J Zuiderduin, D P N Vlasveld, J Huetink. Mechanical properties of polyketone terpolymer/rubber blends [J]. Polymer, 2004, 45:3765-3779.
-
4Jerome Durand, Barbara Milani. The role of nitrogen-donor ligands in the palladium-catalyzed polyketones synthesis[J]. Coordination Chemistry Reviews, 2006, 250:542 - 560.
-
5Antonella Leone, Sebastian Gischig, Giambattista Consiglio. Pd complexes containing non-symmetrical diphosphines in the terpolymerization of ethene, propene and carbon monoxide[ J ]. Journal of Molecular Catalysis A Chemical, 2006,265:98 - 108.
-
6阿克佐公司.聚酮纤维及其制备方法[P].荷兰:911030.27.1,1991-11-27
-
1耐用的供水胶管[J].世界橡胶工业,2009,36(5):57-57.
-
2邹丽萍,陈樑,陈永城,章江洪.CO/C_2H_4交替共聚合成环境友好新型可降解塑料聚酮[J].天然气化工—C1化学与化工,2007,32(1):64-68. 被引量:5
-
3朱林英,陈建,胥会,代文超.纳米碳纤维、纳米碳管的储氢性能研究现状[J].材料导报(纳米与新材料专辑),2015,29(2):23-26. 被引量:1