用过渡金属络合催化剂在水介质中引发烯烃单体的配位聚合

Olefin coordination polymerization initiated by transitional metal complex catalysts in media of water

介绍了乙烯、丁二烯和苯乙烯等单体在水介质中用过渡金属络合催化剂合成有规立构聚合物的研究进展,详细阐述了钴系催化剂在水介质中合成间同1,2-聚丁二烯的研究成果。

Research progress in olefin polymerization catalysed by the transitional metal complex in the media of water including ethylene, butadiene, styrene, etc. was reviewed with 16 references in order to synthesis stereo regular polymer. Study on the synthesis of syndiotactic 1,2-polybutadiene using the cobalt catalyst in water media was introduced in detail.