A new radical way to N,N-dimethylaniline hydroperoxide (DMAHP) and its application in organic synthesis

A new radical way to N,N-dimethylaniline hydroperoxide (DMAHP) and its application in organic synthesis

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摘要 N,N-Dimethylaniline hydroperoxide was obtained when treating N,N-dimethylaniline with NHPI/Co（OAc）2/O2 via a radical reaction mechanism. This intermediate has potential application in the synthesis of some important chemical scaffolds. N,N-Dimethylaniline hydroperoxide was obtained when treating N,N-dimethylaniline with NHPI/Co（OAc）2/O2 via a radical reaction mechanism. This intermediate has potential application in the synthesis of some important chemical scaffolds.

作者 Yi Xu Shi Lei Zhang Wen Hu Duan

机构地区 Shanghai Institute of Materia Medica

出处《Chinese Chemical Letters》 SCIE CAS CSCD 2007年第7期807-810,共4页 中国化学快报（英文版）

关键词 Aerobic oxidation NHPI N N-Dimethylaniline Aerobic oxidation NHPI N,N-Dimethylaniline

分类号 O625.6 [理学—有机化学]

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参考文献15

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Chinese Chemical Letters

2007年第7期

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A new radical way to N,N-dimethylaniline hydroperoxide (DMAHP) and its application in organic synthesis

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