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Dy-BPMPHD-CTMAB荧光体系的研究及其分析应用

Study of the Fluorescence System of Dy(Ⅲ)-BPMPHD-CTMAB and Its Analytical Application
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摘要 本文对Dy-BPMPHD-CTMAB荧光体系进行了研究.研究发现,Dy3+能与BPMPHD和CTMAB形成离子缔合物,并发射出Dy3+的特征荧光峰.Gd3+、Y3+、Lu3+离子能增强体系的荧光强度,产生共发光效应.本文对该共发光体系进行了详细研究,由此提出了快速、灵敏测定痕量稀土Dy3+的新方法,其测定线性范围为1.0×10-7—1.3×10-5mol/L,检出限为2. The fluorescence system of Dy(Ⅲ)-BPMPHD-CTMAB was studied.It was found that Dy3+ could form an ion association complex with BPMPHD and CTMAB and then emitted the intrinsic fluorescence of Dy3+.The fluorescence intensity of the system could be increased by Gd3+、Y3+、La3+. This is a newly found Co-luminescence system. Based on the Co-luminescence system, a rapid, simple and sensitive method was developed for thedetermination of trace amounts of Dy3+. The results indicated that the fluorescence intensity of the system is a linear relationship with the concentration of Dy3+ in the range of 1.0×10-7-1.3×10-mol/L,thedetection limit(S/N=2)is 2.0-×10-8mol/L.
出处 《杭州大学学报(自然科学版)》 CSCD 1997年第2期161-165,共5页 Journal of Hangzhou University Natural Science Edition
基金 省分析测试基金
关键词 荧光光度法 BPMPHD CTMAB dysprosium fluorimetry
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参考文献4

  • 1Li Wenlian,J Alloy Compd,1993年,194卷,1期,19页
  • 2Xu Yongyuan,Talanta,1992年,39卷,7期,759页
  • 3Ci Yunxiang,Anal Chem,1989年,61卷,19期,1063页
  • 4杨鲁勤,兰州大学学报,1988年,24卷,134页

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