Ne^3P0,2）与乙腈的能量转移反应研究

Study of the Energy Transfer Reaction of Ne(~3P_(0,2)) with CH_3CN

在流动余辉装置上，我们研究了亚稳态原子Ｎｅ（＾３Ｐ０，２）与乙腈的能量转移反应，观察到了ＣＮ（Ａ－Ｘ），ＣＮ（Ｂ－Ｘ），ＣＨ（Ａ－Ｘ）的发射谱。计算了ＣＮ（Ａ，Ｂ）的相对振动粒子数布居，并对该反的机理进行了讨论。

Energy transfer reaction from metastable Ne(~3P(0,2)) atom to CH_3CN has been-studied by using flowing afterglow technique. The CN(B-X),CN(A-X) and CH(A-X)emission bands are observed. The vibrational population distribution of CN(A,B) aremeasured and the reaction mechanism discussed.