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4,4′-喹啉酸锌(Ⅱ)配位聚合物(英文)

Zinc(Ⅱ) Coordination Polymer with 4,4′-quinoline Ligand
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摘要 Hydrothermal treatment of racemic atropisomeric ligand diethyl (R,S)-7,7′-dimethyl-4,4′-biquinoline-3,3′-dicarboxylate (DDBD) in the presence of pyridine over 4 days at 140 ℃ with Zn(OAc)2 offers zinc coordination polymer {Zn(DBD)(pyridine)2(H2O)}n{Zn(DBD)(H2O)1/2}n (1), which shows weak fluorescence at about 490 nm at solid state at room temperature. CCDC: 631007. Hydrothermal treatment of racemic atropisomeric ligand diethyl (R,S)-7,7'-dimethyl-4,4'-biquinoline-3,3'-dicarboxylate (DDBD) in the presence of pyridine over 4 days at 140 ℃ with Zn(OAc)2 offers zinc coordination polymer [{Zn(DBD)(pyridine)2(H2O)}n{Zn(DBD)(H2O)n}]n (1), which shows weak fluorescence at about 490 nm at solid state at room temperature. CCDC: 631007.
作者 王威
出处 《无机化学学报》 SCIE CAS CSCD 北大核心 2007年第7期1306-1308,共3页 Chinese Journal of Inorganic Chemistry
基金 东南大学启动基金资助项目
关键词 锌配位聚合物 4 4′-喹啉酸 晶体结构 荧光性质 zinc coordination polymer 4,4'-quinoline acid crystal structure fluorescence
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参考文献6

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