摘要
采用OPA-MBE方法在SrTiO3(STO)衬底上成功制备了Mn0.1Ti0.9O2-δ(MTO)稀磁半导体薄膜.利用X射线衍射仪、X射线光电子能谱仪、紫外可见光分度计以及直流四探针测试仪研究了薄膜的晶体结构、化学组成、光吸收和电荷输运性质.MTO薄膜具有锐钛矿和金红石的混合相,光吸收带边界发生“红移”,电荷输运性质明显提高,室温环境下电阻率仅为37.5Ω.m.
Diluted magnetic semiconductor Mn0.1Ti0.902-δ (MTO) thin film was grown successfully on SrTiO3 (STO) substrate by oxygen plasma assisted molecular beam epitaxy (OPA-MBE). The crystalline structure,chemistry composition,optical absorption,and electrical conductivity properties of the thin film were characterized by X-ray diffraction (XRD) ,X-ray photoelectron spectrometry (XPS),ultraviolet and visible spectrophotometry (UV-Vis), and resistivity measuring instruments with a four-probe array. The MTO thin film has anatase and rutile crystal structures, and the absorption edge is shifted to the lower-energy. The electrical conductivity of the MTO thin film is evidently improved, and the resistivity is only 37. 5Ω· m at room temperature.
基金
国家自然科学基金(批准号:50572124)
广州市科技计划资助项目~~
关键词
Mn0.1Ti0.9O2-δ薄膜
稀磁半导体
OPA-MBE
X射线光电子能谱
Mn0.1Ti0.90z-δ (MTO) thin film
diluted magnetic semiconductor
oxygen plasma assisted molecular beam epi-taxy
X-ray photoelectron spectra