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分子内杂化纳米结构体多面体低聚倍半硅氧烷研究进展 被引量:4

Developments of Hybrid Organic/Inorganic Nanostructure-Polyhedral Oligomeric Silsesquioxane
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摘要 多面体低聚倍半硅氧烷(POSS)是基于化学键合作用形成的分子内杂化体系,其改性后的材料是一类具有广泛潜在应用价值的新型有机-无机杂化材料。文中介绍了多面体低聚倍半硅氧烷单体的结构、性能、单体及其衍生物的合成,以及其改性聚合物材料在航空、航天、卫生、电子等高科技领域内的应用前景。针对国内的研究现状,指出低聚倍半硅氧烷-聚合物杂化体系研究所存在的问题。 Polyhedral oligomeric silsesquioxane (POSS) based hybrid materials have excellent properties and comprehensive applications for the molecule hybrid system based on the chemical bonding. The structure and property as well as synthesis of POSS monomers and their derivatives were described in this review. The potential applications of POSS-polymers were also introduced. At the same time, the existing problem of the study on hybrid POSS-polymers system in our country was discussed.
出处 《高分子材料科学与工程》 EI CAS CSCD 北大核心 2007年第4期24-28,共5页 Polymer Materials Science & Engineering
关键词 多面体低聚倍半硅氧烷 倍半硅氧烷 有机-无机杂化 纳米材料 polyhedral oligomeric silsesquioxane silsesquioxane organic-inorganic hybrid nanocomposites
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