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负载酞菁钴气体扩散电极对氧的催化还原 被引量:1

Catalytic Reduction of Oxygen on Gas Diffusion Electrode Coated with CoPc
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摘要 制备了负载酞菁钴作为氧的电还原催化剂的气体扩散电极,用稳态极化曲线法探讨了压制压力、催化剂负载量、添加聚4-乙烯基吡啶等因素对电极催化活性的影响。 The electrocatalytic reduction of oxygen on the gas diffusion electrode coated with cobalt phthalocyanine(CoPc) was studied systematically by stable polarization curves. The effects of pressure of electrode preparation, CoPc dosage and addition of PVP on electrocatalytic reduction of oxygen were discussed.
出处 《化学与生物工程》 CAS 2007年第7期16-18,29,共4页 Chemistry & Bioengineering
基金 广东省科技计划资助项目(2004B10301010)
关键词 气体扩散电极 氧还原 电催化 酞菁钴 gas diffusion electrode oxygen reduction electrocatalysis cobalt phthalocyanine
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参考文献8

  • 1曾章逸,潘湛昌.Nafion膜电极对氧的催化还原的研究(I)──CoTSPc和CoTMAP的循环伏安对比[J].高等学校化学学报,1994,15(5):737-740. 被引量:6
  • 2潘湛昌,曾章逸,李琼.氧在直接耐晒翠蓝GL修饰电极上的催化还原[J].物理化学学报,1999,15(5):462-466. 被引量:6
  • 3Convet P,Coutanceau C,Crouigneau P,et al.Electrodes modified by electrodeposition of CoTAA complexes as selective oxygen cathodes in a direct methanol fuel cell[J].J Appl Electrochem,2001,31(9):945-952.
  • 4Sridhar P,Perumal R,Rajalakshmi N,et al.Humidification studies on polymer electrolyte membrance fuel cell[J].Power Sources,2001,101(1):72-78.
  • 5麻晓霞,任奇志,马紫峰.金属卟啉类化合物电催化剂研究进展[J].化学世界,2005,46(4):243-246. 被引量:7
  • 6Savadogo O,Xing B J.Hydrogen/oxygen polymer electrode membrance fuel(FEMFC) based on acid-doped polybenzimidazol[J].New Mater Electrochem Syst,2000,3(4):343-347.
  • 7Anson F C,Ni Ching-long,Saveant J M.Reduction of O2 to H2O2 as catalyzed by cobalt(Ⅱ) tetrakis(4-N-methylpyridyl) porphyrin[J].J Amer Chem Soc,1985,107(12):3442-3450.
  • 8Henny S W,Bard A C.Investigation of charge-transport mechanism in Nafion polymer modified electrode[J].J Am Chem Soc,1982,104(14):4811.

二级参考文献39

  • 1曾章逸,潘湛昌.Nafion膜电极对氧的催化还原的研究(I)──CoTSPc和CoTMAP的循环伏安对比[J].高等学校化学学报,1994,15(5):737-740. 被引量:6
  • 2刘婷 胡乃非 等.-[J].高等学校化学学报,1996,17(12):1532-1532.
  • 3曾章逸,J Appl Electrochem,1991年,21卷,973页
  • 4Shu Chingfong,J Am Chem Soc,1990年,112卷,9227页
  • 5Liang Rongzhong,J Electroanal Chem,1988年,246卷,101页
  • 6刘婷,高等学校化学学报,1996年,17卷,12期,1532页
  • 7Deiwen P,J Electroanal Chem,1994年,372卷,269页
  • 8Zhang Yi Z,J Appl Electrochem,1991年,21卷,973页
  • 9Shaojun D,化学学报,1983年,41卷,9期,809页
  • 10Tatsuhiro O, Masanori G, Makoto Y, et al. Electrochem.Soc[J], 1998,145:815-822.

共引文献14

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  • 1潘凯红,张晶,杨姝.空气电极催化层中导电炭材料的研究(II)[J].电源技术,2006,30(3):211-212. 被引量:1
  • 2徐洪峰,董建华,侯向理.银在质子交换膜燃料电池空气阴极内促进氧传递研究[J].电化学,2006,12(4):434-438. 被引量:2
  • 3SATOSHI F.Analysis of oxygen reduction rate in a proton exchange membrane fuel cell[J].Energy Conversion and Management, 2001, 42:1121-1131.
  • 4RAMOUSSE J, DESEURE J, LOTTIN O,et al.Modelling of heat, mass and charge transfer in a PEMFC single cell[J].J Power Sources, 2005,145:416-427.
  • 5BERNING T, DJILALI N, A 3D,multiphase, multicomponent model of the cathode and anode of a PEM fuel cell [J]. J Power Sources, 2003, 150(12): A1589-AI598.
  • 6KEIZO H,NAGAKAZU F.Preparation of gas diffusion electrodes by electrophoretic deposition [J]. J Electrochem Soc, 2004, 151 (3): A354-A357.
  • 7SRINIVASAN S, HURWITZ H D, BOCKRIS J O M.Fundamental equations of electrochemical kinetics at porous gas-diffusion electrodes [J].J Chemical Physics, 1967,46(8 ):3108-3122.
  • 8CLARK B J,DOROTHY G.Fuel Cells:Their Electrochemistry[M]. New York:McGraw-Hill Inc, 1969.
  • 9NEWMAN J S,TOBIAS C W.Theoretical analysis of current distribution in porous electrode [J].J Electrochem Soc, 1962,109: 1183-1191.
  • 10ZHU M,XU X Z, SU R,et al.Current and overpotential distribution mathematical model of the porous electrode based on the three- phase boundary length [J].J Electrochem Soc,2005,152 (3):A511- A515.

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