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表面活性剂在HCl中对钢的缓蚀协同效应 被引量:6

Synergistic effect on inhibition by surfactants for steel in hydrochloric acid solution
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摘要 用失重法和电化学法研究了在1.0 mol/L HCl中阴离子表面活性剂油酸钠(SO)和非离子表面活性剂聚乙二醇辛基苯基醚(OP)对冷轧钢的缓蚀协同作用。研究结果表明,单独的SO和OP对冷轧钢具有一定的缓蚀作用,为混合型缓蚀剂,且在钢表面的吸附符合Temkin吸附模型。当两者复配后产生了明显的缓蚀协同效应,最大缓蚀率可达92%。 The synergistic effect on inhibition anionic surfactant of sodium oleate (SO) and nonionic surfactant of polyethylene glycol mono - (p) octyl phenyl ether (OP) for cold rolled steel (CRS) in 1.0 mol/L HCl solution was investigated by weight- loss and polarization methods. The results showed that both SO and OP had moderate inhibitive effect on CRS corrosion, and acted as mixed -type inhibitor for cold rolled steel. The adsorption of SO (OP) on CRS surface accords with the Temkin adsorption isotherm. Incorporation of sodium SO and OP significantly improves the inhibi- tion performance, which is synergistic inhibition effect. Polarization studies show that the complex of SO with OP acts as a mixed - type inhibitor. The maximum inhibition efficiency was about 92%.
出处 《清洗世界》 CAS 2007年第7期1-5,共5页 Cleaning World
关键词 盐酸 油酸钠 聚乙二醇辛基苯基醚 缓蚀协同效应 吸附 steel hydrochloric acid sodium oleate polyethylene glycol mono - (p) octyl phenyl ether synergism adsorption
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