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苯选择加氢制环己烯的研究进展 被引量:14

STUDY ON THE PREPARATION OF HYDROGEN PEROXIDE BY AIR OXIDATION OF ISOPROPANOL AT ATMOSPHERIC PRESSURE
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摘要 综述了 Ru催化剂上苯液相选择加氢制环己烯的研究进展 ,着重介绍了化学混合法制备的 Hydrogen peroxide has found a lot of uses as fine organic chemical product, which is produced mainly by electrolysis in high cost at present in this country. In contrast hydrogen peroxide is prepared abroad from isopropanol at 1.0 MPa pressure in low cost with acetone as byproduct in newly built equipment.In this paper isopropanol is oxidized by air of 2.5 mL/s·100 g at 80 ℃ and atmospheric pressure for 48 h to give hydrogen peroxide with yield of 63% and acetone as byproduct with purity of 99.5% and yield of 73%, using benzoperoxide of 4%(w) as initiator and 8quinolinol of 0.5%(w) as stablizer for H 2O 2. The procedure is simple and safe,and can be operated under mild conditions that make it easy for commercial purpose.
出处 《精细石油化工》 CAS CSCD 北大核心 1997年第3期46-50,共5页 Speciality Petrochemicals
关键词 苯选择加氢 环己烯 化学混合法 钌催化剂 hydrogen peroxide isopropanol acetone oxidation reaction
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