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水解聚丙烯酰胺盐水溶液表观粘度的数学模拟(Ⅲ)——表观粘度与剪切速率的通用关系式 被引量:5

MATHEMATICAL SIMULATION OF APPARENT VISCOSITY FOR HYDROLYZED POLYACRYLAMIDE- SALT SOLUTION (III) AN UNIVERSAL RELATIONSHIP BETWEEN APPARENT VISCOSITY AND SHEAR RATE
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摘要 通过对水解聚丙烯酰胺盐水溶液的流动曲线的分析,提出了两点假设.据此分别建立了Meter-Bird式常数γ_(1/2)和P_α与零剪切粘度η_0间的经验式,及表观粘度η_α和剪切速率γ间的通用 Meter-Bird式.用此方程式与本文(Ⅰ)报通用 MHS方程式和(Ⅱ)报式(4) 联用,模拟水解聚丙烯酰胺盐水溶液的表观粘度,取得了较好的结果. Two assumptions were put forward as a result of analysis of the flow curves of hy-drolyzed polyacrylamide-salt solution. Based on these, the relationships between the constantsγ1/2 and Pα in Meter s equation and zero-shear viscosity η0 were established, and therefore a universal Meter's equation relating apparent viscosity ηa with shear rate γ was deduced. The equationand the MHS equation in part ( Ⅰ ) and the equation (4) in part ( Ⅱ ) can be used to simulate theapparent viscosity for the system and good results were obtained.
出处 《化工学报》 EI CAS CSCD 北大核心 1997年第1期80-84,共5页 CIESC Journal
关键词 水解 聚丙烯酰胺 聚电解质 溶液流变学 粘度 hydrolyzed polyacrylamide polyelectrolyte solution rheoiogy non-Newtonian flow apparent viscosity
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