期刊文献+

离子液体在精细化工中的应用 被引量:2

Application of Ionic Liquids in Fine Chemical Industry
原文传递
导出
摘要 综述了离子液体在Heck反应、氧化反应、加氢还原反应、傅-克反应和醇的卤代反应中的应用。氯铝酸离子液体催化的合成丁基苯的傅-克反应中,室温下反应3m in即可反应完全,而在离子液体中进行的烯烃加氢反应只需反应6h。离子液体也能加快氧化反应的反应速度。 The applications of ionic liquids in Heck reaction, oxidation, hydroreduction, Friedel-Crafts and halogenation of alcohol were summarized. Using chloroaluminate ionic liquid as catalyst, butylbenzene was synthesized catalytically in 3 minutes under room temperature by the Friedel-Crafts reaction, and the olefin hydrogenation in ionic liquid only needed 6 hours. Ionic liquid could also quicken the reaction speed of oxidation.
出处 《精细与专用化学品》 CAS 2007年第15期10-13,共4页 Fine and Specialty Chemicals
关键词 离子液体 HECK反应 傅-克反应 加氢还原反应 ionic liquid Heck reaction Friedel-Crafts hydroreduction
  • 相关文献

参考文献24

  • 1[1]Wasserscheid P,Keim W.Ionic liquids-new "Solutions" for transition metal catalysis[J].Angewandte Chemie,2000,39:3772~3789
  • 2[2]Robin D,Kenneth R,Seddon R.Ionic liquids-solvents of the future[J].Science,2003,302:792~793 Earle M J,Seddon K R.Ionic liquids green solvents for the future[J].Pure Appl Chem,2000,72(7):1391~1398
  • 3[3]Jeffrey A,Boon J A,Levisky J,et al.Friedel-Crafts reactions in ambient-temperature molten salts[J].J Org Chem,1986,51:480~483
  • 4[4]Kaufmann D E,Nouroozian M,Henze H.Molten salts as an efficient medium for palladium-catalyzed C-C coupling reactions[J].Synlett,1996:1091~1092
  • 5[5]Adrian J,Martyn J,Earle D,et al.The heck reaction in ionic liquids:a multiphasic catalyst system[J].Organic Letters,1999,1(7):997~1000
  • 6[6]Claudia C,Cassol A P,Umpierre G M,et al.The role of Pd nanoparticles in ionic liquid in the Heck reaction[J].J Am Chem Soc,2005,127:3298~3299
  • 7[7]Choong Eui Song,Eun Joo Roh.Practical method to recyle a chiral (salen)Mn epoxidation catalyst by using an ionic liquid[J].Chem Commun,2000,837~838
  • 8[8]Joshua Howarth.Oxidation of aromatic aldehydes in the ionic liquid[Bmim]PF6[J].Tetrahedron Letters,2000,(41):6627~6629
  • 9[9]Nan Jiang,Arthur J R.Vanadium-catalyzed selective aerobic alcohol oxidation in ionic liquid[Bmim]PF6[J].Tetrahedron Letters,2007,(48):273~276
  • 10[10]Paulo A Z,Suarez J E,Dullius S E,et al.Polyhedron,1996,15(7):1217~1219

同被引文献25

引证文献2

二级引证文献2

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部