摘要
在理想恒温条件下,通过BZ反应中各反应步骤活化能的分析,阐明了BZ反应体系中间物浓度变量演化方程与温度的关系;根据线性稳定性分析法,确定了以温度T及模型参数h(NaBrO3浓度为定值)为参数的BZ反应振荡动力学分区,使BZ反应振荡阈值的理论更加系统化.通过BZ反应振荡温度阈值的研究。
The authors elucidates the temperature effects on the evolution of the intermediate concentrations in the perfect isothermal BZ reacting system,by analysis of the activation energy of the elementary steps.Using the analysis of linearized stability,it further gives the dynamic rigime of oscillatory behavior on the temperature model parameter plane under condition of constant bromate concentration.This work systematizes sthe oscillafion threshold theory of the BZ reaction.In addition,it predicates a new way to obtain information about the activation energies of the elementary steps,through the study on temperature threshold of the BZ oscillafing reaction.
出处
《四川大学学报(自然科学版)》
CAS
CSCD
北大核心
1997年第2期216-220,共5页
Journal of Sichuan University(Natural Science Edition)
基金
国家自然科学基金
关键词
起振温度阈值
BZ反应
化学振荡
耦合温度振荡
oregonator model,BZ oseillating reaction,threshold temperature for oscillation,analysis of linearized stability