新型水溶性杯[4]芳烃的合成和性质研究

Study on the Synthesis and Novel Property of Water-soluble Calyx[4]arene

通过曼尼希反应合成了一种具有良好水溶性的上缘取代杯[4]芳烃:5,11,17,23-四[脯氨酸-N-甲基]-25,26,27,28-四羟基杯[4]芳烃(Pro-C4)。用紫外光谱法、电化学方法研究了其与十二烷基磺酸钠(SDS)、Cu2+形成的多元配合物。

A water soluble calix [ 4 ] arene, 5, 11,17,23-tetra （ proline- N-methylene）-25,26,27, 28-tetrahydroxyl calix-[4] arene （Pro-C4） was synthesized by Mannish reaction. The complex formed by Pro-C4, SDS and Cu^2＋ was studied by UV and electrochemical methods.