期刊文献+

绿色阻垢剂聚天冬氨酸的制备与性能研究 被引量:2

The Synthesis and Efficiency Assessment of Green Scale Inhibiter Polyaspartic Acid
下载PDF
导出
摘要 采用马来酸酐与氨水进行溶液聚合的方法制备聚天冬氨酸,利用静态阻垢法评价了聚天冬氨酸的阻垢性能。结果表明:聚天冬氨酸对ρ(Ca2+)=300mg/L,ρ(HCO3-)=300mg/L的水样阻垢率可以达到90%以上;在ρ(HCO3-)低于400mg/L时,药剂的阻垢率可达到100%;当ρ(HCO3-)大于400mg/L后,药剂阻垢性能降低明显。聚天冬氨酸具有良好的生物降解性,生物降解率可以达到70%。 In this paper, polyaspartic acid was obtained by the polymerization of maleic anhydride and ammonia . The efficiency of scale inhibition was assessed by static scale inhibition tests. The result shows that scale inhibition rate of the polyaspartic acid can reach more than 90% for ρ(Ca2+)=300 mg/L and ρ(HCO3-)=300 mg/L with the scale inhibition rate 100% for ρ(HCO3-)lower than 400 mg/L. The efficiency of the scale inhibitors decreased obviously when ρ(HCO3-) was higher than 400 mg/L. The polyaspartic acid has high biodegradation efficiency, and its biodegradation rate can reach over 70%.
出处 《油气田环境保护》 CAS 2007年第1期31-33,共3页 Environmental Protection of Oil & Gas Fields
基金 黑龙江省教育厅科学技术研究项目资助 项目编号:10551006
关键词 绿色阻垢剂 聚天冬氨酸 马来酸酐 合成 生物降解 green scale inhibiter polyaspartic acid maleic anhydride synthesis biodegradation
  • 相关文献

参考文献4

二级参考文献32

  • 1Low K C, Wheeler A P, Koskan L P. Green Chemistry Applied to Corrosion and Scale Inhibitors[J]. Adv Chem Set, 1996, 248:99 - 111.
  • 2Robert J Ross, Kim C Low, James E Shannon. Green Chemistry Applied to Corrostion and Scale Inhibitors [J ]. Material Performance, 1997, (4) :52-57.
  • 3Koskan Larry P. Polyaspartic acid as a calcium sulfate and a barium sulfate inhibitor[P]. US 5116513,1991.
  • 4Gasparyan E E. Explosive amination of carboxylic acid[J]. Zh Fiz Khim,1990,64(6): 1 701-1 703.
  • 5Koskan L P, Low K C. Polyaspartic acid as a calcium carbonate and a calcium phosphate inhibitor[P]. WO 92 - 16 462,1992.
  • 6Koskan L P. Process for the manufacture of anhydro polyamino acid and polyamino acids[P]. US 5 057 597,1991.
  • 7Mozo G Y, et al. Production of polysuccinimide in cyclic carbonate solvent[P]. US 5 756 595,1998.
  • 8Mukoama M, Hayashi T. Manufacture of succinimide polymers and aspartic acid polymers with excellent biodegradablity [P]. JP 0 931 195,1997.
  • 9Masayuki T, Taskeshi N. Novel method of synthesizing polysuccinimide and its copolymeric derivatives by acid-catalysed polyeondensation of L - aspartic acid [J ]. Polymer, 1997,38 ( 18 ) : 4 733 - 4 736.
  • 10Tomida M. Novel method of synthesizing poly (succinimide) and its copoly-meric derivs by acid catalyzed polycondensation of L - aspartic acid[J]. Polymer, 1996,37(19) :4 435 -4 437.

共引文献74

同被引文献23

引证文献2

二级引证文献29

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部