摘要重点介绍了国内外近年来在二氧化硅介孔膜的制备与应用方面的最新进展,并对其制备与应用研究前景进行了展望。Recent progresses of the preparation and applications of mesoporous silica films are reviewed, also prospected.
1Kresge C T,Leonowicz M E,Roth W J,et al.Ordered Mesoporous Molecular Sieves Synthesized by a Liquid-Crystal Template Mechanism[J].Nature,1992,359:710-712
2Beck J S,Vartuli J C,Roth W J,et al.A New Family of Mesoporous Molecular Sieves Prepared with Liquid Crystal Templates[J].J.Am.Chem.Soc.,1992,114:10834-10843
3Stupp S I,Braun P V.Molecular manipulation of microstructures:biomaterials,ceramics,and semiconductors.Science,1997,277:1242
4Yang H,Coombs N,Sokolov I,et al.Free-standing and oriented mesoporous silica films growm at the air-water interface[J].Nature,1996,381:589-592
5Yang H,Kuperman A,Coombs N,et al.Synthesis of oriented films of mesoporous silica on mica[J].Nature,1996,379:703-705
6Tolbert S H,Schaffer T E,Feng J L,et al.A new phase of oriented mesoporous silicate thin films[J].Chem Mater,1997,9:1962-1967
7Ogawa M,Kikuchi T.Preparation of self-standing transparent films of silica-surfactant mesostructured materials and the conversion to porous silica films[J].Adv Mater,1998,10:1077-1080
8Ryoo R,Ko C H,Cho S J,et al.Optically transparent,single-crystal-like oriented mesoporous silica films and plates[J].J Phys Chem B,1997,101:10610-10613
9Martin J E,Anderson M T,dinekJ O,et al.Synthesis of periodic mesoporous silica thin films[J].Langmuir,1997:4133-4141
10Miyata H,Kuroda K.Formation of a continuous mesoporous silica film with fully aligned mesochannels on a glass substrate[J].Chem Mater,2000,12:49-54
