摘要
One of characteristics of Cr2O3-containing refractory is excellent corrosion resistance. However, there is a problem of hexavalent chromium, which is noxious to the human body, and easily formed by the reactions among the refractory and CaO, Na2O and/or K2O in slag. In this article, the reason why the Cr2O3-containing refractory has excellent corrosion resistance, the forming conditions of hexavalent compounds, and the methods for suppressing generation of the compound, are described as a base of further development of excellent refractories.
One of characteristics of Cr2O3-containing refractory is excellent corrosion resistance. However, there is a problem of hexavalent chromium, which is noxious to the human body, and easily formed by the reactions among the refractory and CaO, Na2O and/or K2O in slag. In this article, the reason why the Cr2O3-containing refractory has excellent corrosion resistance, the forming conditions of hexavalent compounds, and the methods for suppressing generation of the compound, are described as a base of further development of excellent refractories.