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离子液体及其在石油化工中的应用

Ionic Liquids and Its Applications in Petrochemical Technology
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摘要 离子液体即在室温或接近室温下呈液态的、完全由离子构成的物质,作为环境友好和"可设计性"溶剂正在引起越来越多的重视。它具有熔点低、蒸气压小、酸性可调及良好的溶解度、粘度和密度等特点。本文综述了离子液体的组成、分类、性质、制备和纯化,详细说明了其在石油化工中的应用,如在烷基化、氢化、脱硫等反应中的应用。 The ionic liquids keep liquid state at or near room temperature. As environmentally benign and "designer" solvents, they are attracting more and more attentions. They have characteristic of low melting point, low vapor pressure, adjustable acidity, strong solubility and high viscosity. The composition, classification, property, preparation and purification of them were reviewed in this paper. The applications in petrochemical technology were discussed, such as alkylation, hydrogenation, and desulfuration etc.
出处 《广东化工》 CAS 2007年第9期24-27,共4页 Guangdong Chemical Industry
关键词 离子液体 性质 制备 纯化 石油化工 ionic liquids property preparation purification petrochemical technology
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  • 1Welton T.Room-temperature ionic liquids for synthesis and catalysis[J].Chem.Rev.,1999,99(8):2071-2083.
  • 2顾浩,方岩雄,张焜.室温离子液体的性质和应用[J].精细与专用化学品,2005,13(7):10-11. 被引量:11
  • 3Gu Z,Brennecke J F.Volume expansivities and isothermal compressibilities of imidazolium and pyridinium-based Ionic Liquids[J].J.Cbem Eng.Data,2002,47(2):339-345.
  • 4Bonbote P,Dias A P,Papageorgiou N,et al.Hydrophobic,highly conductive ambient-temperature molten salts[J].Inorg.Chem,1996,35(2):1168-1678.
  • 5张保芳,蒲敏,陈标华,刘坤辉.一类新型绿色环保的介质材料——咪唑类离子液体[J].材料科学与工程学报,2006,24(1):165-168. 被引量:24
  • 6张晓燕,李健,王国良,刘金龙,张治军,吴志申,孙殿成.室温离子液体在石油化工中的应用[J].河南化工,2006,23(2):1-4. 被引量:6
  • 7Bradaric C J,Downard A,Kennery C,et al.Industrial preparation of phosphonium ionic liquids[J].Journal of the Royal Society of Chemistry,Green chemistry,2003,5(2):143-152.
  • 8Holbrey J D,Reichert W M,Swatloski R P.Efficient halide free synthesis of new,low cost ionic liquids:1,3 dialkylimidazolium salts containing methyl-and ethyl-sulfate anions[J].Journal of The Royal Society of Chemistry,Green Chemistry,2002,4(5):407-413.
  • 9Varma R S,Namboodiri V V.An expeditious solvent-free route to ionic liquids using microwaves[J].Journal of The Royal Society of Chemistry.Chem.Commun,2001,7(1):643-644.
  • 10Hirao M,Sugimoto H,Ohno H.Novel room-temperature molten salts by neutralization of amines[J].J.Electro.Chem.Soc.,2000,147(11):4168-4172.

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