摘要
采用微波合成法合成了一系列新的含不同β-二酮的环金属铂配合物。在微波反应条件下,反应时间从32h减少到30min左右。同时,对环金属铂配合物的吸收和发射光谱、热稳定性,磷光寿命的影响进行了讨论。
Microwave synthetic method has been developed for the synthesis of a series of new cyclometalated platinum complexes with different β-diketonate ligands,and its reaction time is greatly reduced from 32h to several minutes.Moreover,effects of β-diketonate ligands on thermal stability,phosphorescent emission and lifetimes of cyclometalated platinum complexes have been discussed.
出处
《化学研究与应用》
CAS
CSCD
北大核心
2007年第9期991-993,共3页
Chemical Research and Application
基金
国家自然科学基金资助项目(20472060)
关键词
微波辐射(MWI)
环金属铂配合物
光致发光
磷光寿命
microwave irradiation（MWI）
cyclometalated platinum complexes
photoluminescence,phosphorescent lifetime.
