Preparation and Property of Bisphenol A Bis (diphenyl phosphate) Oligomer
Preparation and Property of Bisphenol A Bis (diphenyl phosphate) Oligomer
摘要
Bisphenol A bis（diphenyl phosphate） oligomer（BDP） is prepared successfully from the reactants consisting of phosphorus oxyehloride （POCl3）, bisphenol A and phenol with a Friedel-Crafts catalyst. The resultant products were examined with thermtygravimetrie analysis （TGA） and high performance liquid chro- matography（HPLC）. Thermogravimetry data shows that BDP decomposes at 375℃ when 5 % weight lost. Experiments results show that catalyst is preferably AICI3 and the amount of it is preferably 1% relative to bisphenol A by mole. POCl3/bisphenol A mole ratio is preferably about 5：1 to 6：1. Experiments unclosed that a seal apparatus is very important to the properties of product.
Bisphenol A bis（diphenyl phosphate） oligomer（BDP） is prepared successfully from the reactants consisting of phosphorus oxyehloride （POCl3）, bisphenol A and phenol with a Friedel-Crafts catalyst. The resultant products were examined with thermtygravimetrie analysis （TGA） and high performance liquid chro- matography（HPLC）. Thermogravimetry data shows that BDP decomposes at 375℃ when 5 % weight lost. Experiments results show that catalyst is preferably AICI3 and the amount of it is preferably 1% relative to bisphenol A by mole. POCl3/bisphenol A mole ratio is preferably about 5：1 to 6：1. Experiments unclosed that a seal apparatus is very important to the properties of product.
参考文献10
-
1Nikolaus J,Reinhard P,Andreas C,et al.Process for preparing phosphoric acid esters[].US.2002
-
2Cefn B,Johan WA.Fog reductionin polyurethane foam using phosphate esters[].US.1999
-
3Danielle A B,Ronald L P.Process for the formation of hydrocarbyl bis(hydrocarbyl phosphate):[].US.1998
-
4Danielle A B,Ronald P L.4-Hydroxy-alkylphenyl diphenyl phosphate flame rerardants[].US.1998
-
5Danielle A B,Ronald L P.Process for the formation of hydrocarbyl bis(hydrocarbyl phosphate)[].US.2000
-
6Alan MA,Danielle A B.Phenolphthalein bis(dihydro-carbyl phosphate)compounds[].US.1993
-
7Gunkel L T,Barda HJ.Process for preparing aryldis-phosphate esters[].EP.1992
-
8Nakamura S,Noguchi K.Process for the preparation of condensed phosphoric esters[].USB.2002
-
9Balabanovich AI.Poly(butylene terephthalate)fire re-tarded by bisphenol A bis(diphenyl phosphate)[].Journal of Analytical and Applied Pyrolysis.2004
-
10WILLIAM B HARROD,DIRK KLOBUCAR W.Bisphenol-A bis(diphenyl phosphate)-based flame retardant[].US Pa-tent: B.2001
