摘要
应用微观粒子波动和分子轨道理论,解释生物标志化合物在沉积体系中自身独有的"电子离域-外质子磁旋反应"的重排机理。首先阐明生物标志化合物立体异构重排的理论依据;然后分别探讨了萜、甾烷类立体异构重排和成熟度对应关系;极性、非极性生物标志化合物异构体重排和油气运移对应关系。
In this paper, the stereoisomer rearrangement of biomarker compound for the exclusive reaction form the electronic off-domain to the out-proton magnetic rotation is interpreted in the sedimentary system in terms of the micro-particle wave motion and the molecular orbital theory. First of all, the theoretic basis for the stereoisomer rearrangement of biomarker compound is illustrated, and then the corresponding relations between the sterane/terpane stereoisomer rearrangement and maturity, as well as the polarity/non-polarity and petroleum migration are discussed, respectively.
出处
《新疆石油地质》
CAS
CSCD
北大核心
2007年第5期523-528,共6页
Xinjiang Petroleum Geology
关键词
生物标志物
异构体
粒子
分子
biomarker compound
stereoisomer rearrangement
particle
molecule
