摘要
研究了层状氢氧化镁铝焙烧产物对SCN-的吸附行为,考察了焙烧温度、吸附温度、时间、pH值等因素对吸附的影响.在SCN-初始浓度为25 mg/L,温度为40℃,焙烧物投加量为2 g/L,pH值为6的条件下,4 h达到吸附平衡,SCN-脱除率可达96.91%.吸附过程符合Langmu ir等温方程式,主要是单分子层的吸热吸附.
The adsorption performance of calcined Mg/Al layered double hydroxides for thiocyanate ion was studied. The effects of calcined temperature of Mg/Al layered double hydroxides and adsorption temperature, adsorption time, pH value were investigated. The removal rate of SCN- is 96.91%, when original concentration of thiocyanate ion is 25 mg/L, adsorption temperature is40 ℃, sorbent dosage is 2 g/L, pH value is 6 and adsorption time is 4 h. Equilibrium data were fitted very well to the Langmuir mode in the entire saturation concentration range, indicating that the adsorption was endothermic process and of monomolecular layer.
出处
《化学研究》
CAS
2007年第3期75-79,共5页
Chemical Research
基金
国家自然科学基金资助项目(20477041)
关键词
SCN-
层状氢氧化镁铝
焙烧
吸附
脱除
thiocyanate ion
Mg/Al layered double hydroxides
calcination
adsorption
removal