化学引发的烯类单体与酪素的接枝共聚反应的研究进展

Progress on Copolymerization of Casein and Vinyl Monomers by Chemical Initiation

酪素与烯类单体的接枝共聚产物广阔的应用前景,越来越引起人们的关注。而引发体系的选择对接枝效果和接枝聚合产品的性能至关重要。从引发机理,引发效果等各个方面出发,对近年来不同引发剂引发的各种烯类单体与酪素的接枝共聚反应进行了总结和评述,并对酪素接枝反应引发剂的发展趋势作了展望。

The graft copolymer of casein and vinyl monomers have exhibited broad application prospect, and also have attracted more and more attention. In the eopolymerization, the iniation system has great effect on the eopolymerization process and the function of eopolymer products. In this paper,the initiators used in graft eopolymerization of casein with various kinds of vinyl monomers in recent years were reviewed. The initiation mechanisms and initiation efficiencies were also included. Furthermore, the prospect of these initiators was foreeaeted.