摘要
酪素与烯类单体的接枝共聚产物广阔的应用前景,越来越引起人们的关注。而引发体系的选择对接枝效果和接枝聚合产品的性能至关重要。从引发机理,引发效果等各个方面出发,对近年来不同引发剂引发的各种烯类单体与酪素的接枝共聚反应进行了总结和评述,并对酪素接枝反应引发剂的发展趋势作了展望。
The graft copolymer of casein and vinyl monomers have exhibited broad application prospect, and also have attracted more and more attention. In the eopolymerization, the iniation system has great effect on the eopolymerization process and the function of eopolymer products. In this paper,the initiators used in graft eopolymerization of casein with various kinds of vinyl monomers in recent years were reviewed. The initiation mechanisms and initiation efficiencies were also included. Furthermore, the prospect of these initiators was foreeaeted.
出处
《化学世界》
CAS
CSCD
北大核心
2007年第9期561-565,共5页
Chemical World
基金
国家自然科学基金重点项目(50333050)
教育部科学技术研究重点项目(204109)
广东省"千百十"工程优秀人才培养基金项目(Q02117)
关键词
酪素
烯类单体
接枝共聚
自由基机理
引发剂
casein
vinyl monomers
graft eopolymerization
radical mechanism
initiation