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酞菁配合物对锂-亚硫酰氯电池正极的催化作用 被引量：10

Studies on Catalytic Mechanism of Li/SOCl_2 Batteries by Metal Phthalocyanine Complexes
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摘要 合成过渡金属酞菁配合物MPc(M=Mn(Ⅱ),Fe(Ⅱ),Co(Ⅱ),N i(Ⅱ),Cu(Ⅱ)),研究MPc及其中心离子对L i/SOC l2电池正极的催化作用,并提出相关催化机理. Effects of metal phthalocyanine comlexes MPc （ M = Mn （ Ⅱ）, Fe （ Ⅱ ）, Co （ Ⅱ ）, Ni （ Ⅱ ）, Cu （ Ⅱ ） ） as electrochemical catalysts on the performance of Li/SOCl2 batteries have been examined at constant resistance. And the reasons of MPc affecting the discharged voltage and discharged also brought forward. A few new viewpoints on the catalytic mechanism of the phthalocyanine complexes were proposed time of Li/SOCl2 batteries were reduction of thionyl chloride by
作者 许占位 孙庆津 苏碧云 车兔林 宋艳虹 李要民 赵建社
机构地区 西北大学化学系陕西省物理无机化学重点实验室 西安机电信息研究所
出处 《电化学》 CAS CSCD 北大核心 2007年第3期293-296,共4页 Journal of Electrochemistry
基金 国家自然科学基金(No.20671076)资助
关键词 过渡金属 酞菁配合物 锂/亚硫酰氯(Li/SOCl2) 催化机理 transition metal phthalocyanine complexes lithium/thionyl chloride catalytic mechanism
分类号 TM912 [电气工程—电力电子与电力传动]
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参考文献9

  • 1王莹澈,蔡圣同.锂储备电池在引信电源中的应用及前景[J].探测与控制学报,2000,22(4):45-48. 被引量：11
  • 2LIUJing(刘景) GEHonghua(葛红花) ZHOUGuoding(周国定) etal.Research status of lithium/thionyl chloride battery.Battery,(15):408-410.
  • 3XU Zhanwei (许占位),SU Biyun (苏碧云),SONG Yanhong (宋艳虹),et al.Research status of lithium/thionyl chloride battery cathode[C].In:Proceedings of the 4th National Physic-Inorganic Symposium.Linfen:Shanxi Normal University Press,2006.198-199.
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  • 5Lee S B,Pyun S I,Lee E J.Effect of the compactness of the lithium chloride layer formed on the carbon cathode on the electrochemical reduction of SOCl2 electrolyte in Li/SOCl2 batteries[J].Electrochimica Acta,2001,47 (6):855-864.
  • 6Doddapaneni N.Low-temperature performance of high-rate lithium/thionyl chloride cells[C]// In:Proceedings of the 30th Power Sources Symposium,Atlantic:N J,1982,169-171.
  • 7Bernstein P A,Lever A B P.Two electron oxidation of cobalt phthalocyanines by thionyl chloride:implications for lithium/thionyl chloride batteries[J].Inorg Chem,1990,29:608-612.
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二级参考文献4

  • 1MIL—HDBK—757（AR）,美国军用手册—引信[S]. 1994,4,15.
  • 2D.Shapira, et al. Reserve Lithium Inorganic Battery for Electronic Fuzing[A]. Proceeding of the 32nd International Power Sources Symposium (1)[C]. New york: The Eelectrochemical Society, INC. 1986:298.
  • 3S corda, et al. Li/SOCl2 Reserve Bipolar Artillery Battery[A]. Proceeding of the 32nd International Power Sources Symposium (1)[C]. New york: The Eelectrochemical Society, INC. 1986:292.
  • 4G Voorn, A New Lithium Reserve Battery for Artillery-Fuze Applications[A]. Proceeding of the 33nd International Power Sources Symposium[C]. New york: The Eelectrochemical Society, INC. 1988:294.

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二级引证文献17

电化学
2007年 第3期

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