摘要
The reaction of CuI with cinchonine （an organic donor-acceptor chromophore） afforded a homochiral 3D diamondoid network [Cu4I4（cinchonine）2]n （1） containing a cubane cluster （Cu4I4） as a connecting node. This is the first homochiral coordination polymer with diamondoid nets containing a cluster as a connecting note. Its thermal stability and solid state optical properties such as fluorescence, circular dichroism and second-harmonic generation response were also reported.
The reaction of CuI with cinchonine （an organic donor-acceptor chromophore） afforded a homochiral 3D diamondoid network [Cu4I4（cinchonine）2]n （1） containing a cubane cluster （Cu4I4） as a connecting node. This is the first homochiral coordination polymer with diamondoid nets containing a cluster as a connecting note. Its thermal stability and solid state optical properties such as fluorescence, circular dichroism and second-harmonic generation response were also reported.
基金
Project supported by 973 project （No. 2025103）, the National Natural Science Foundation of China （No. 2003028400） and the Distinguished Young Scholar Fund from the National Natural Science Foundation of China （No. 2006CB806104）.
