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Sr,Ti双位掺杂铬酸镧电导性能研究 被引量:4

Electrical Conductivity of Sr and Ti doped LaCrO_3 Ceramics
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摘要 分别用固相反应法和凝胶注方法制备了固体氧化物燃料电池(SOFCs)阳极用La_xSr_(1-x)Cr_yTi_(1-y)O_3(LSCT)系列化合物,用SEM、XRD等手段研究了其显微结构,并测试了该材料的电导率,综合以上三项对La_xSr_(1-x)Cr_yTi_(1-y)O_3系列用作固体氧化物燃料电池阳极材料的性能进行评价,筛选了配方,并对制备工艺进行了讨论。 Sr and Ti co-doped LaCrO3 (LaxSr1-xCryTi1-yO3) powders were synthesized from carbonate and oxides based on the principle of solid state reaction and gel-casting. XRD patterns indicated the perovskite structure was formed without any second phases when sintering at 1450 ℃ for 6 h by gel-casting, which was lower than by solid state reaction at 100 ℃. The total electrical conductivity was greatly depended on the ingredient, and reached the maximum when x=0.2, y=0.3.
出处 《稀有金属材料与工程》 SCIE EI CAS CSCD 北大核心 2007年第A02期593-595,共3页 Rare Metal Materials and Engineering
基金 国家自然科学基金项目(50232020 50572042)
关键词 阳极材料 固体氧化物燃料电池 双位掺杂铬酸镧 anode materials electrical conductivity doped LaCrO3
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参考文献4

  • 1HanMinfang(韩敏芳),PengSuping(彭苏萍).SOFC(固体氧化物燃料电池)[M].Beijing:Science Press,2004
  • 2Takuya Hashimoto, Naoto Tsuzuki, Akira Kishi et al. Solid Statelonics[J], 2000, 132:183
  • 3Pudmich G, Boukamp B A, Gonzalez-Cuenca M et al. Solid State lonics[J], 2000, 135:433
  • 4Tao Shanwen, John T S Irvine. Journal of The Electrochemical Society[J], 2004, 151(2): A252

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