摘要
Layered double hydroxides(LDHs) are a class of synthetic anion clays, characterized by the formula [MⅡ1-xMⅢx(OH)2]x+(An-)x/n5yH2O(where M=metal and A=anion, usually carbonate)[1-3]. A large number of LDHs with a wide variety of MⅡ-MⅢ cation pairs including MⅠ-MⅢ(e.g., Li-Al) and MⅡ-MⅣ(e.g., Co-Ti) have been reported. Thus the identities of the cations(MⅠ, MⅡ, MⅢ and MⅣ) and the interlayer anion(An-) together with the value of the stoichiometric coefficient(x) may vary widely, giving rise to a large class of isostructural materials. As a result,
Layered double hydroxides(LDHs) are a class of synthetic anion clays, characterized by the formula [MⅡ1-xMⅢx(OH)2]x+(An-)x/n5yH2O(where M=metal and A=anion, usually carbonate)[1-3]. A large number of LDHs with a wide variety of MⅡ-MⅢ cation pairs including MⅠ-MⅢ(e.g., Li-Al) and MⅡ-MⅣ(e.g., Co-Ti) have been reported. Thus the identities of the cations(MⅠ, MⅡ, MⅢ and MⅣ) and the interlayer anion(An-) together with the value of the stoichiometric coefficient(x) may vary widely, giving rise to a large class of isostructural materials. As a result,
基金
Supported by Excellent Young Scholars Research Fund of Beijing Institute of Technology(No.000Y05-22)
the Key Labora-tory of Beijing City on Preparation
Processing of Novel Polymer Materials(No.SYS100100420) in Beijing University of ChemicalTechnology.