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松节油加氢热解产物中单萜烷类化合物的初步研究 被引量:5

Identification of monoterpanes in hydrogenated turpentine
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摘要 用雷尼镍为催化剂对松节油进行了加氢实验,获得顺蒎烷、反蒎烷、莰烷、异莰烷等单萜烷类化合物,采用气相色谱"反吹、微流控"技术的色谱-质谱分析方法,测得了它们的保留时间和质谱图,为进一步研究原油或抽提物轻馏分中单萜烷类化合物的地球化学意义提供了一些基础性数据。 Raney nickel catalyst was used in hydrogenation of the turpentine and c-pinane, t-pinane, camphene and isocamphane and some other monoterpanes were determined. The retention time and mass spectrum chromatogram of the monoterpanes were obtained by both FID and MSD analyzer equipped with backflush and micro - flow controller. This study provides some basic data for further research on the geochemistry significance of monoterpanes in the light fraction of crude oil and extraction of source rock.
出处 《地球化学》 CAS CSCD 北大核心 2007年第6期535-538,共4页 Geochimica
基金 国家自然科学基金(40573030)
关键词 单萜烷 原油轻馏分 色谱-质谱 有机地球化学 monoterpane light fraction of oil GC/MS organic geochemistry
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