1,4-二氮杂双环[2·2·2]辛烷催化的有机化学反应

Organic Reactions Catalyzed by 1, 4-Diazabicyclo[2.2.2]octane

综述了有机小分子催化剂1,4-二氮杂双环[2.2.2]辛烷(DABCO)在有机合成反应中的应用与发展。这种有机小分子催化的反应大多数条件温和、操作简单;相对过渡金属而言,对环境友好;在一定条件下,这种催化剂可以回收再利用。

The organic reactions catalyzed by 1, 4-diazabicyclo[2.2.2]octane （DABCO） are reviewed. Most of the reactions start conveniently from available substrate and proceed under mild conditions. The reactions are environmentally friendLY, and the catalyst can be recycled in some cases. The perspectives on DABCO catalyzed reactions are pointed out.