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N-[ω-(三丁基锡甲氧基)烷基]邻苯二甲酰亚胺的合成及其光环化反应 被引量：5

Synthesis of N-(tributylstannylmethoxy)alkylphthalimides and Their Cyclization by Photocatalysis Induced via Single Electron Transfer
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摘要 烷基二醇与三丁基锡碘甲烷反应得三丁基锡甲氧基烷基醇(2a^2 e);2(或其衍生物)与邻苯二甲酰亚胺反应合成了N-[ω-(三丁基锡甲氧基)烷基]邻苯二甲酰亚胺(5a^5 e),其结构经NMR和MS表征。5在光诱导下,由单电子转移引发,经分子内自由基偶合,高产率(85%~99%)地获得可控制反应位置的大环化合物。 Tributylstannylmethoxy,alkyl-alcohols （2a- 2e） were prepared from alkyl-diol and Bu3SnCH2I. N-（tributylstannylmethoxy） alkylphthalimides（5a - 5e） were synthesized by reaction of 2（or derivatives） and phthalimide. The structures were characterized by NMR and MS. Photoreactions of 5 in methanol and acetone induced by single electron transfer produce cyclized products in high yields（85% - 99% ）.
作者 金英学 谭广慧 刘斯斯
机构地区 黑龙江八一农垦大学生命科学技术学院
出处 《合成化学》 CAS CSCD 2007年第5期570-575,共6页 Chinese Journal of Synthetic Chemistry
基金 黑龙江省教育厅海外学人科研资助项目(1152hq23) 黑龙江省农垦总局科技资助项目(HIVKXIVZD-006)
关键词 单电子转移 光环化 三丁基锡 邻苯二甲酰亚胺 合成 single electron transfer photocyclization tributylstannyl phthalimide
分类号 O626 [理学—有机化学]
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参考文献12

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同被引文献40

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  • 2Wang, X.-Y.; Kimyonok, A.; Weck, M. Chem. Commun. 2006, 3933.
  • 3Haldi, A.; Kimyonok, A.; Domercq, B.; Hayden, L. E.; Jones, S. C.; Marder, S. R.; Weck, M.; Kippelen, B. Adv. Funct. Mater. 2008, 18, 3056.
  • 4Osakada, Y.; Kawai, K.; Fujitsuka, M.; Majima, T. Nucleic Acids Res. 2008, 36, 5562.
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  • 7Sung, N. K.; Cho, D. W.; Choi, J. H.; Choi, K. W.; Yoon, U. C.; Hajime, M.; Mariano, P. S. J. Org. Chem. 2007, 72, 8831.
  • 8Yoon, U. C.; Jin, Yo X.; Oh, S. W.; Park, C. H.; Park, J. H.; Campana, C. F.; Cai, X. L.; Duesler, E. N.; Mariano, P. S. J. Am. Chem. Soc. 2003, 125, 10664.
  • 9Choi, D. W.; Choi, J. H.; Oh, S. W.; Quan, C. S.; Yoon, U. C.; Wang, R. T.; Yang, S. R.; Mariano, P. S. J.. Am. Chem. Soc. 2008, 130, 2276.
  • 10Yoon, U. C.; Jin, Y.-X.; Oh, S. W.; Choi, D. W.; Park, K. H.; Mariano, P. S. J. Photochem. Photobiol. A: Chem. 2002, 150, 77.

引证文献5

二级引证文献8

合成化学
2007年 第5期

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