摘要
A supramolecular complex, [Kpic]n (pic-is picratol, (NO2)3C6H2O-), has been synthesized unexpectedly in acetone solution, and characterized by elemental analysis, IR and X-ray crystallography. In the complex, the K+∶pic-is 1∶1, and one K(Ⅰ) ion is surrounded by six picrate anions, one picrate anion can coordinate to six K(Ⅰ) ions. The coordination number of every potassium atom is eight. Interestingly, the picratol adopts an eight-coordinated ideal mode unreported. CCDC:630627.
A supramolecular complex, [Kpic]n （pic^- is picratol, （NO2）3C6H2O^-）, has been synthesized unexpectedly in acetone solution, and characterized by elemental analysis, IR and X-ray crystallography. In the complex, the K^＋：pic^- is 1：1, and one K（I） ion is surrounded by six picrate anions, one picrate anion can coordinate to six K（I） ions. The coordination number of every potassium atom is eight. Interestingly, the picratol adopts an eightcoordinated ideal mode unreported. CCDC： 630627.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2007年第10期1809-1811,共3页
Chinese Journal of Inorganic Chemistry
基金
甘肃省教育厅基金资助项目(No.0604-01)
兰州交通大学"青蓝"人才工程基金资助项目(No.QL-03-01A)
关键词
钾(I)配合物
合成
晶体结构
potassium（I） complex
synthesis
crystal structure
