摘要
以3,3—二甲基—(1H—1,2,4—三唑)—2—丁酮为配体(L)和不同铜盐反应,合成了六个Cu(Ⅱ)配合物CuL_2Cl_2、CuL_2Br_2、CuL_3(NO_3)_2、CuL_3(BF_4)_2、CuL_4(ClO_4)_2和CuL_4SO_4·4H_2O),通过元素分析、摩尔电导、红外,研究了配合物的组成、结构和性质,并测定了CuL_4(ClO_4)_2的晶体结构。
A series of Cu(Ⅱ ) complexes of ligand(3,3 - dimethyl- 1 -(1H - 1,2,4 -triazol-1 -y1 ) - 2 - butanone) were prepared and characterised by means of elemental analyses,electrical conductances,IR. The crystal structure of CuL4(ClO4)2 was determined by X -ray diffraction method. The relationship between composition ,properties and struetures -was studied.
出处
《苏州大学学报(自然科学版)》
CAS
1997年第1期57-60,共4页
Journal of Soochow University(Natural Science Edition)