2-(对叔丁基-苯基)-苯并噻唑合铱(Ⅲ)的乙酰丙酮配合物的合成及性质

Synthesis and Properties of 2-(4-tert-butyl-phenyl)ben zothiazolate Iridium(Ⅲ) acetylacetone complex

以对叔丁基苯甲酰氯、邻氨基苯硫酚为原料,通过与铱的三氯化物配合,合成了一种新型金属铱(Ⅲ)的2-(对叔丁基-苯基)苯并噻唑配合物(t-bt)2Ir(acac),对产物进行了核磁、红外、质谱和元素分析等结构表征及溶解性、热性能和发光性能的研究.

A new phosphorescent 2-（4-tert-butyl-phenyl）-benzothiazolate Iridium（Ⅲ） acetylacetone complex is synthesized with 4-tert-butylbenzoyl chloride, 2-aminothiophenol, and Iridium trichloride anhydrate. The complex is characterized by ^1H NMR,mass spectrometry,FT-IR and elemental analysis. The UV-vis absorption and photoluminescence of the complex is investigated.