摘要
氯铂酸与苯并-15-冠-5(L)固态配合物经元素分析、红外光谱、紫外光谱、热谱、X-射线粉末衍射分析证明,此固态配合物是1∶2型(H_2PtCl_6·2L)分子间化合物.同时,结合核磁共振谱,讨论其可能的分子结构,并测试其溶解性和摩尔电导.
The syntheses and properties of chloroplatinic acid with benzo-15-crown-5 crown ether solid complex is studied. It is a new kind of crown ether coordination compound, which is of 1∶2 type and identified by element analysis, IR spectrum, UV spectrum, TG DTA and X-ray. Its solubility have been detected. The molecular structure of this compound have been studied by NMR spectrum.
出处
《贵金属》
CAS
CSCD
北大核心
1990年第3期18-23,共6页
Precious Metals
关键词
铂配合物
合成
性能
冠式化合物
Platinum complex, Synthesis, Properties, Crown ether compounds
