摘要
综述了近几年环氧烷烃、二氧化碳和甲醇一步法合成碳酸二甲酯的研究进展,详细阐述了当前所用到的催化剂的结构,性质和催化机理,简单探讨了该合成路线的反应机理,并分析了以后需要深入研究的方向。
Recent research works on onepot synthesis of dimethyl carbonate from epoxides, carbon dioxide abd methanol were reviewed. The structure, character and catalytic mechanism of variouscatalysts were introduced. The mechanism of this synthesis reaction was discussed simply, and the future research directions were also analyzed.
出处
《天然气化工—C1化学与化工》
CAS
CSCD
北大核心
2007年第5期72-75,78,共5页
Natural Gas Chemical Industry
基金
国家自然科学基金(20072005)
关键词
碳酸二甲酯
环氧烷烃
二氧化碳
甲醇
一步合成
dimethyl carbonate
epoxide
carbon dioxide
methanol
one-pot synthesis