期刊文献+

High efficient acetalization of carbonyl compounds with diols catalyzed by novel carbon-based solid strong acid catalyst 被引量:3

High efficient acetalization of carbonyl compounds with diols catalyzed by novel carbon-based solid strong acid catalyst
原文传递
导出
摘要 The novel carbon-based acid catalyst has been applied to catalyzing the acetalization and ketalization. The results showed that the catalyst was very efficient with the average yield over 93%. The novel het- erogeneous catalyst has the advantages of high activity, wide applicability even to 7-membered ring acetals, strikingly simple workup procedure, non-pollution, and reusability, which will contribute to the green process greatly. The novel carbon-based acid catalyst has been applied to catalyzing the acetalization and ketalizaUon. The results showed that the catalyst was very efficient with the average yield over 93%. The novel het- erogeneous catalyst has the advantages of high activity, wide applicability even to 7-membered ring acetals, strikingly simple workup procedure, non-pollution, and reusability, which will contribute to the green process greatly.
出处 《Chinese Science Bulletin》 SCIE EI CAS 2007年第21期2892-2895,共4页
基金 Supported by the National High-Tech R&D Program (863 Program) (Grant No. 2005AA320010-2)
关键词 多环芳烃 绿色反应 炭化过程 二醇 acetalization, polycyclic aromatic carbon-based solid strong acid, green process
  • 相关文献

参考文献10

  • 1Nakajima K,Tomita I,Hara M, et al.A stable and highly active hybrid mesoporous solid acid catalys[].Advanced Materials.2005
  • 2Anastas P T,Kirchhoff M M.Origins, current status, and future challenges of green chemistry[].Accounts of Chemical Research.2002
  • 3Misono M,Acad C R.Heterogeneous catalysis[].Sci Ser Iic.2000
  • 4Smith K,El-Hiti G A,Gamal A, et al.Acetylation of aromatic ethers using acetic anhydride over solid acid catalysts in a solvent-free sys- tem Scope of the reaction for substituted ethers[].Org Biomol Chem.2003
  • 5Hara M,Yoshida T,Takagaki A, et al.A carbon material as a strong protonic acid[].Angewandte Chemie International Edition.2004
  • 6Toda M,Takagaki A,Okamura M, et al.Green chemistry: Biodiesel made with sugar catalyst[].Nature.2005
  • 7Okamura M,Takagaki A,Toda M, et al.Acid-catalyzed reactions on flexible polycyclic aromatic carbon in amorphous carbon[].Chemistry of Materials.2006
  • 8De Simone J M.Practical Approaches to Green Solvents[].Science.2002
  • 9Brendan Horton.Green chemistry puts down roots[].Nature.1999
  • 10Anastas Paul T,Zimmerman Julie B.Design through the 12 principles of green engineering[].Environmental Sciences.2003

同被引文献20

引证文献3

二级引证文献4

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部