过渡金属配合物构型畸变探究

Research into Distortion of Complexes Structure of Transitional Metal

分析了八面体配合物和四面体配合物畸变的原因,给出了判断八面体配合物和四面体配合物畸变的一般方法:配合物是否发生畸变要看中心离子电子云是否对称分布,若对称分布,就具有规则的八面体或四面体构型,否则,将会发生变形。

This paper analyzes the cause of distortion of octahedron complexes and tetrahedron complexes and states the general methods to judge the distortion. The distortion of complexes depends on the symmetry of the distribution of central ion electron cloud. The symmetric distribution will lead to ordinate octahedron and tetrahedron. Otherwise, distortion will happen.