期刊文献+

催化反应过程绿色集成系统 被引量:3

Green integrated system of catalytic reaction
下载PDF
导出
摘要 在化工生产过程中,通常需要多步化学反应才能获得目标产物。为了最大限度地节约能源、提高资源利用率和减少排放,多步反应过程集成是重要途径。通过对化学反应过程集成系统的分析,基于不同催化剂活性相的组合尺度,提出将多个催化反应构成的系统划分为纳米尺度、微米尺度和宏观尺度3类绿色集成系统,并通过典型实例进行了论述。认为催化剂活性相以纳微尺度复合的多功能催化剂是实现多步反应一步化的有效方法之一。 Usua reactions. Integr lly, in chemical process, the products are obtained through multi-step chemical ation of the multi-step reactions is a matter of great importance for saving energy, improving utilization of resource and cutting down the emission. In this paper, based on the combination scale of the different catalytic active sites, the integrated system, which is composed of several catalytic reactions, is divided into three sub-systems: nano-scale, micro-scale and macro-scale. The typical examples are discussed separately. It was considered that the multi-functional catalysts, in which the active sites were combined in nano/micro scale, was one of the promising methods for the integration of multistep chemical reactions.
出处 《化工学报》 EI CAS CSCD 北大核心 2007年第11期2689-2696,共8页 CIESC Journal
基金 科技部重大基础研究前期研究专项(2005CCA06100) 国家自然科学基金项目(20636030 20476022)~~
关键词 纳米尺度 微米尺度 宏观尺度 催化反应 集成系统 nano-scale micro scale macro scale catalytic reaction integrated system
  • 相关文献

参考文献32

  • 1Wang Yanji(王延吉),Zhao Xinqiang(赵新强).Green Catalytic Process and Technology(绿色催化过程与工艺).Beijing:Chemical Industry Press,2002:76-98.
  • 2Li Yuan, Zhao Xinqiang, Wang Yanji. Synthesis of dirnethyl carbonate from methanol, propylene oxide and carbon dioxide over KOH/4A molecular sieve catalyst. Applied Catalysis A : General, 2005, 279 ( 1/2 ) : 205-208.
  • 3夏建超,毛东森,陈庆龄,唐颐.合成气一步法制二甲醚双功能催化剂的研究进展[J].石油化工,2004,33(8):788-794. 被引量:36
  • 4Liu Hongwei (刘宏伟). Study on dimethyl ether-synthesis from syn-gas, kinetics and deactivation of bifunctional catalysts[D]. Shanghai: East China University of Science & Technology, 2005.
  • 5贾美林,李文钊,徐恒泳,葛庆杰,侯守福,肖海成,迟克彬,郭继宁,李影辉,孔繁华.含氮合成气直接制二甲醚的Cu基催化剂研究[J].分子催化,2002,16(1):35-38. 被引量:17
  • 6Clerici M G, Bellussi G, Romano U. Synthesis of propylene oxide from propylene and hydrogen peroxide catalyzed by titanium silicalite. Journal of Catalysis, 1991, 129:159-167.
  • 7Taramasso M, Perego G, Notari B. Preparation of porons crystalline synthetic material comparised silicon and titanium oxides: US, 4410501. 1983.
  • 8Meiers R, Dingerdissen U, Holderich W F. Synthesis of propylene oxide from propylene, oxygen, and hydrogen catalyzed by palladium-platinum-containing titanium silicate. Journal of Catalysis, 1998, 176:376-386.
  • 9Han Yi-Fan, Lunsford J H. Direct formation of H2O2 from H2 and O2 over a Pd/SiO2 catalyst: the roles of the acid and the liquid phase. Journal of Catalysis, 2005, 230: 313-316.
  • 10Motokura K, Fujita N, Mori K, Mizugaki T, Ebitani K, Kaneda K. Development of one-pot reaction systems using heterogeneous catalysts based on hydrotalcite and montmorillonite clays. Catalysts & Catalysis, 2005, 47 (6): 439-441.

二级参考文献75

  • 1杨晓霞,张敏华,王晓燕.多相催化反应合成碳酸二甲酯的研究[J].天然气化工—C1化学与化工,2000,25(4):15-17. 被引量:4
  • 2蔡光宇,刘中民,石仁敏,何长青,杨立新,孙承林.合成气经由二甲醚制取低碳烯烃[J].天然气化工—C1化学与化工,1994,19(5):26-30. 被引量:28
  • 3谢光全.二甲醚的应用[J].天然气化工—C1化学与化工,1996,21(3):52-54. 被引量:14
  • 4葛庆杰,黄友梅,张天莉.合成气直接制取二甲醚的双功能催化剂[J].天然气化工—C1化学与化工,1996,21(5):19-22. 被引量:47
  • 5吕胜初.二甲醚脱水制低碳烯烃[J].天然气化工,1982,12(1):31-31.
  • 6[1]Saleh R Y,Michaelson R C,Suciu E N, et al. Process for Manufacturing Dialkyl Carbonates from Urea and Alcohol. WO 9 517 369.1995
  • 7[2]Ryu Y J. Process for Making Dialkl Carbonates. US 5 902 894. 1999
  • 8[3]Cho T,Tamura T, Cho T, et al. Process for Preparing Dialkyl Carbonates. US 5 534 649. 1994
  • 9Romano U,Tesel R,Maurl M M, et al. Synthesis of dimethyl carbonate from methanol, carbon monoxide, and oxygen catalyzed by copper compounds[J]. Ind Eng Chem Prod Res Dev,1980,19(3):396-403.
  • 10西平圭吾 松崎德雄 田中秀二.アルキルナイトヲイト法炭酸ジメチル制造法の开发と实用化[J].触媒,1995,37(2):68-69.

共引文献153

同被引文献20

  • 1江爱朋,邵之江,陈曦,方学毅,耿大钊,郑小青,钱积新.乙烯生产流程中联塔模拟与优化[J].化工学报,2006,57(9):2128-2134. 被引量:17
  • 2王慧,刘水刚,张文郁,赵宁,魏伟,孙予罕.高稳定性CaO-ZrO_2固体碱催化剂的表征和催化性能[J].化学学报,2006,64(24):2409-2413. 被引量:19
  • 3LIRong-sheng(李荣生),ZHENKai-ji(甄开吉),WANGGuo-jia(王国甲).BasisofCatalysis(催化作用基础)[M].2ndEd(第二版).Beijing(北京):SciencePress(科学出版社),1990.
  • 4LIShi-yao(李时瑶) CAIGuang-yu(蔡光宇) WANGQing-xia(I清遐) etal.Effect of the high temperature steam treatment on the surface property and the catalytic activity of HZSM-5 zeolite (水热处理对HZSM-5沸石表面性质及催化性能的影响).催化学报,1987,:47-52.
  • 5Struijk J, d'Angremond M, Lucas-de Regt W J M, et al. Partial liquid phase hydrogenation of benzene to cyclohexene over ruthenium catalysts in the presence of an aqueous salt solution: I. Preparation, characterization of the catalyst and study of a number of process variables [J]. Applied Catalysis A: General, 1992, 83(2): 263-295.
  • 6Makoto M, Tomoyuki I. New catalytic technologies in Japan [J]. Catalysis Today, 1999, 51(3-4): 369-375.
  • 7Peschel W, Adrian T, Rust H, et al, Method for the production of cyclohexanol from benzole: ZL 03805208.3 [P]. 2006-08-30.
  • 8XUE W, SONG Y, WANG Y, et al. Effect of hydrazine hydrate on the Ru-Zn/SiO2 catalysts performance for partial hydrogenation of benzene [J]. Catalysis Communications, 2009, 11(1): 29-33.
  • 9LIU J, ZHU Y, LIU J, et al. Discrimination of the roles of CdSO4 and ZnSO4 in liquid phase hydrogenation of benzene to cyclohexene [J]. Journal of Catalysis, 2009, 268(1): 100-105.
  • 10王基铭.过程系统工程技术与中国石化可持续发展[J].化工学报,2007,58(10):2421-2426. 被引量:5

引证文献3

二级引证文献4

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部