摘要
Fe3O4 catalyst supported on spherical γ-Al2O3 was prepared with and without ultrasonic treatment during the impregnation step,and the heterogeneous catalytic oxidation of dimethoate wastewater was conducted with Fenton reagent.Then,the physical and chemical properties of the catalysts were analyzed by means of XRD,ICP-AES and SEM,especially the effect of Fe3O4 dispersity on γ-Al2O3.The results showed that the activity of the supported catalysts prepared with ultrasonic treatment for dimethoate was higher than those without ultrasonic treatment and the corresponding degradation rate doubled those of the catalyst obtained by impregnation.The probable cause was that for catalysts prepared with ultrasonic treatment,Fe3O4 was well dispersed on the catalyst surface with small particle size,or existed in non-crystalline amorphous state,and Fe content on the catalyst surface was higher than those without ultrasonic treatment.
Fe3O4 catalyst supported on spherical γ-Al2O3 was prepared with and without ultrasonic treatment during the impregnation step, and the heterogeneous catalytic oxidation of dimethoate wastewater was conducted with Fenton reagent. Then, the physical and chemical properties of the catalysts were analyzed by means of XRD, ICP-AES and SEM, especially the effect of Fe3O4 dispersity on γ-Al2 O3. The results showed that the activity of the supported catalysts prepared with ultrasonic treatment for dimethoate was higher than those without ultrasonic treatment and the corresponding degradation rate doubled those of the catalyst obtained by impregnation. The probable cause was that for catalysts prepared with ultrasonic treatment, Fe3O4 was well dispersed on the catalyst surface with small particle size, or existed in non-crystalline amorphous state, and Fe content on the catalyst surface was higher than those without ultrasonic treatment.
出处
《化工学报》
EI
CAS
CSCD
北大核心
2007年第11期2805-2809,共5页
CIESC Journal
