CuCl·C_4H_4N_2配位聚合物的水热合成、表征及晶体结构研究

Synthesis,Characterization and Crystal Structure of CuCl·C_4H_4N_2 Complex

采用水热法合成了CuCl.C4H4N2配位聚合物,以X-射线衍射分析晶体结构,结果表明该配位聚合物为单斜晶系,空间群P2/c,a=0.381 46(10)nm,b=0.635 43(14)nm,c=1.148 8(3)nm,α=90.00(°),β=96.05(2)(°),γ=90.00(°),V=0.276 91(12)nm3,Z=2.采用紫外-可见光谱、荧光光谱、傅里叶变换红外光谱、元素分析、X光电子能谱分析、热重-示差扫描量热分析和变温磁化强度分析等手段,对其结构进行表征.

CuCl·C4H4N2 complex was systhesized under hydrothermal condition. Its crystal structure was determined at room temperature. This complex crystallized in the monoclinic system, space group, P2/ c,a = 0.381 46（10） nm,b = 0.635 43（14） nm,c = 1. 148 8（3） nm,α= 90.00（°）,β= 96.05（2） （°）,γ = 90.00（°）,V = 0. 276 91（12） nm^3,Z = 2. And its structure was further characterized by ultraviolet visuahle spectrum, fluorescence spectrum, fourier transform infrared spectrum, elementary analysis, X-ray photoelectron analysis, thermogravimetric-differential scanning calorimetry analysis, the strength of magnetization mutative temperature analysis and so on.