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一个新颖的三维配位化合物[Co(Mepydc)(H_2O)_4]n·2.5nH_2O(Mepydc=3-甲基-2,5-吡啶二甲酸)的合成和结构表征

Synthesis and Structure Characterization of a Novel 3-D Complex [Co(Mepydc)(H_2O)_4]n·2.5nH_2O (Mepydc=3-methylpyridine-2,5-dicarboxylic acid)
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摘要 3-甲基-2,5-吡啶二甲酸在水溶液中与CoCl2.6H2O反应,生成了一个新颖的三维配位络合物[Co(Mepydc)(H2O)4]n.2.5nH2O,通过元素分析、红外光谱、TG-DSC分析及X-射线法表征了它的结构. Reaction of 3 - methylpyridine- 2,5 - dicarboxylic acid with CoCl2·6H2O in aqueous solution give rise to a three - dimensional complex [ Co (Mepydc) ( H2O) 4 ] n·2.5 nH2O ( Mepydc = 3- methylpyridine- 2,5 - dicarboxylic acid). It has been characterized by elemental analyses, infrared spectra (IR) spectrum, TG and DSC analysis and single crystal X- ray diffraction.
出处 《内蒙古民族大学学报(自然科学版)》 2007年第5期504-509,共6页 Journal of Inner Mongolia Minzu University:Natural Sciences
关键词 钴络合物 3-甲基-2 5-吡啶二甲酸 三维络合物 表征 Cobalt complex 3 - Methylpyridine- 2,5 - dicarboxylic acid Three- dimensional complex Characterization
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