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SDBS/乙二醇/水混合体系中温度对碳酸钙结晶的影响 被引量:4

Infiuence of Temperature on Calcium Carbonate Crystallization in SDBS/Glycol/Water System
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摘要 通过模拟生物矿化过程,把表面活性剂十二烷基苯磺酸钠(SDBS)加入到乙二醇和水混合溶液中,搅拌一段时间后加入一定浓度的Na2CO3水溶液,然后分别于20?、40?、60?、80?下缓慢滴加CaCl2水溶液进行反应。XRD和TEM发现,不同温度下生成的碳酸钙具有不同的晶体结构和形貌,分析了其可能的成因。 In this paper, by modeling biomineralization processes, adding surfactant sodium dodecylbenzensulfonatc (SDBS) into mixed solution of glycol and water. After agitating a period of time, 0.3mol/L Na2CO3 solution was given into SDBS/glycolAvater system, then 0.3mol/L CaCl2 was dribbled slowly into the mixed solution at different temperature (20℃, 40℃, 60℃, 80℃) to react with Na2CO3 mixed solution. XRD and TEM found that samples synthesized in different temperature had different.crystal structures and morphologies. And the possible reasons were analyzed.
出处 《非金属矿》 CAS CSCD 北大核心 2007年第6期8-10,37,共4页 Non-Metallic Mines
基金 国家自然科学基金重点项目(40331001)
关键词 温度 球霰石 文石 十二烷基苯磺酸钠 混合溶剂 temperature vaterite aragonite sodium dodecylbenzcnsulfonate mixed solvent
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