摘要
研究了以PhCH2Cl/MoCl3（OC8H17）2/PPh3体系引发异戊二烯的原子转移自由基聚合,所得聚合物的相对分子质量与转化率呈线性增加,相对分子质量分布为1.9～2.2。紫外光谱分析表明,该聚合反应符合原子转移自由基聚合机理。
Atom transfer radical polymerization （ATRP） of isoprene has been rarely reported in the open literature up to now[1].In this paper
the ATRP of isoprene using a novel initiation system, benzyl chloride （PhCH2Cl） as the initiator, MoCl3（OC8H17）2 as the catalyst, and PPh3 as the ligand, was investigated.
出处
《合成橡胶工业》
CAS
CSCD
北大核心
2007年第3期235-235,共1页
China Synthetic Rubber Industry
基金
Supported by National Natural Science Foundation of China (50473030 )
