摘要
A series of W-type ferrites with the composition ofBal-xLaxCo2Fe16O27(where, x =0.0, 0.05, 0.10, 0.15, 0.20 and 0.25) were prepared by solid-state reaction method. The structure transformations of the ferrites were examined by XRD, DTA-TG and XPS, and the microwave-absorbing properties were investigated by evaluating the permeability and permittivity of materials(μτ,ετ, ). The results showed that the phase-transition temperature increased with the addition of La^3+ content, and a single-phase was formed at 1250℃ at last. Microwave properties were obviously improved as a result of the substitution of La^3+ for Ba^2+ at the frequency range of 0.5 - 18.0 GHz.
A series of W-type ferrites with the composition ofBal-xLaxCo2Fe16O27(where, x =0.0, 0.05, 0.10, 0.15, 0.20 and 0.25) were prepared by solid-state reaction method. The structure transformations of the ferrites were examined by XRD, DTA-TG and XPS, and the microwave-absorbing properties were investigated by evaluating the permeability and permittivity of materials(μτ,ετ, ). The results showed that the phase-transition temperature increased with the addition of La^3+ content, and a single-phase was formed at 1250℃ at last. Microwave properties were obviously improved as a result of the substitution of La^3+ for Ba^2+ at the frequency range of 0.5 - 18.0 GHz.
基金
Project supported by the Natural Science Foundation of Jilin Province of China (20000512-2)
Institute of Applied Chemistry of Jilin Province, China (R020202k)